Hydrogenation of imines catalysed by ruthenium(II) complexes based on lutidine-derived CNC pincer ligands.

نویسندگان

  • Martín Hernández-Juárez
  • Mónica Vaquero
  • Eleuterio Álvarez
  • Verónica Salazar
  • Andrés Suárez
چکیده

The preparation of new Ru(II) complexes incorporating fac-coordinated lutidine-derived CNC ligands is reported. These derivatives are selectively deprotonated by (t)BuOK at one of the methylene arms of the pincer, leading to catalytically active species in the hydrogenation of imines.

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Ruthenium(II) Complexes Containing Lutidine-Derived Pincer CNC Ligands: Synthesis, Structure, and Catalytic Hydrogenation of C-N bonds.

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عنوان ژورنال:
  • Dalton transactions

دوره 42 2  شماره 

صفحات  -

تاریخ انتشار 2013